The approach relies on engineered materials consisting of nanostructured semiconductor alloy crystals. Heat is a vibration of matter — technically, a vibration of the atomic lattice of a material — just as sound is. Such vibrations can also be thought of as a stream of phonons — a kind of “virtual particle” that is analogous to the photons that carry light. The new approach is similar to recently developed photonic crystals that can control the passage of light, and phononic crystals that can do the same for sound.
The spacing of tiny gaps in these materials is tuned to match the wavelength of the heat phonons, explains Martin Maldovan, a research scientist in MIT’s Department of Materials Science and Engineering and author of a paper on the new findings published Jan. 11 in the journal Physical Review Letters.
“It’s a completely new way to manipulate heat,” Maldovan says. Heat differs from sound, he explains, in the frequency of its vibrations: Sound waves consist of lower frequencies (up to the kilohertz range, or thousands of vibrations per second), while heat arises from higher frequencies (in the terahertz range, or trillions of vibrations per second).
In order to apply the techniques already developed to manipulate sound, Maldovan’s first step was to reduce the frequency of the heat phonons, bringing it closer to the sound range. He describes this as “hypersonic heat.”
“Phonons for sound can travel for kilometers,” Maldovan says — which is why it’s possible to hear noises from very far away. “But phonons of heat only travel for nanometers [billionths of a meter]. That’s why you couldn’t hear heat even with ears responding to terahertz frequencies.”
Heat also spans a wide range of frequencies, he says, while sound spans a single frequency. So, to address that, Maldovan says, “the first thing we did is reduce the number of frequencies of heat, and we made them lower,” bringing these frequencies down into the boundary zone between heat and sound. Making alloys of silicon that incorporate nanoparticles of germanium in a particular size range accomplished this lowering of frequency, he says.
Reducing the range of frequencies was also accomplished by making a series of thin films of the material, so that scattering of phonons would take place at the boundaries. This ends up concentrating most of the heat phonons within a relatively narrow “window” of frequencies.
Following the application of these techniques, more than 40 percent of the total heat flow is concentrated within a hypersonic range of 100 to 300 gigahertz, and most of the phonons align in a narrow beam, instead of moving in every direction.
As a result, this beam of narrow-frequency phonons can be manipulated using phononic crystals similar to those developed to control sound phonons. Because these crystals are now being used to control heat instead, Maldovan refers to them as “thermocrystals,” a new category of materials.
These thermocrystals might have a wide range of applications, he suggests, including in improved thermoelectric devices, which convert differences of temperature into electricity. Such devices transmit electricity freely while strictly controlling the flow of heat — tasks that the thermocrystals could accomplish very effectively, Maldovan says.
Most conventional materials allow heat to travel in all directions, like ripples expanding outward from a pebble dropped in a pond; thermocrystals could instead produce the equivalent of those ripples only moving out in a single direction, Maldovan says. The crystals could also be used to create thermal diodes: materials in which heat can pass in one direction, but not in the reverse direction. Such a one-way heat flow could be useful in energy-efficient buildings in hot and cold climates.
Other variations of the material could be used to focus heat — much like focusing light with a lens — to concentrate it in a small area. Another intriguing possibility is thermal cloaking, Maldovan says: materials that prevent detection of heat, just as recently developed metamaterials can create “invisibility cloaks” to shield objects from detection by visible light or microwaves.
Rama Venkatasubramanian, senior research director at the Center for Solid State Energetics at RTI International in North Carolina, says this is “an interesting approach to control the various frequencies of the phonon spectra that conduct heat in a solid-state material.”
The modeling used to develop this new system “needs to be further developed,” Venkatasubramanian adds. “The theory of what wavelengths of phonons, and at what temperatures, contribute to how much heat transport is a complex problem even in simpler materials, let alone nanostructured materials, and these will have to be factored in — so this paper will trigger more interest and study in that direction.”